Pdf methane steam reforming has been simulated, analyzed and optimized with the aid of aspen plus, in this work. Different technologies are available to produce syngas from natural gas including catalytic steam methane reforming smr, twostep reforming. Relationship between the oxygen available in the solid for methane reforming and the oxygen release rate during methane reforming to achieve the treatment of 1500 tch 4 day with a 10 m. This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen.
Steam methane reforming, or smr, processes feedstocks, ranging from natural gas to light naphtha, mixed with steam to produce a hydrogen rich syngas effluent, with a typical h 2 co ratio of 3. Pdf assessments for lowtemperature methane reforming. High temperature accelerates the reaction rates of steam methane reforming and carbon dioxide reforming. Simulation, sensitivity analysis and optimization of hydrogen production by steam reforming of methane using aspen plus. Analysis of hydrogen production from methane autothermal. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. Steam reforming sr is more and more studied to produce. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Carbon dioxide reforming of methane to syngas by thermal plasma. Since these compounds are hydrocarbons, use the pengrobinson thermodynamic package.
Steam methane reforming steam power plants nuclear power systems hydrogen production. Methane and carbon dioxide are major feedstocks of an autothermal reformer atr and a co2 reformer, respectively. The good news is, you can use the case study tool in hysys to generate these numbers and still make your tee time. Autothermal reforming atr technology was used for the production of the synthesis gas since it is one of the best ways of producing methanol in large capacities. Process simulation to obtain a synthesis gas with high concentration of hydrogen 31 the addition of steam in the second reactor serves to the dual purpose of maintaining the reactor temperature and either to ensure that the excess of methane from the natural gas stream is consumed. Combined steam reforming and partial oxidation of methane to synthesis gas under electrical discharge korada supat and sumaeth chavadej the petroleum and petrochemical college, chulalongkorn university, bangkok 10330, thailand. Simulation of hydrogen production for mobile fuel cell. Process design simulation of h2 production by sorption enhanced. Using hysys, you can model and simulate the steam ethane reforming with propylene. Process assessments for lowtemperature methane reforming. The resultants of the reaction include hydrogen, carbon monoxide and a relatively small amount of carbon dioxide. C2pt catalyst process technology by gerard b hawkins managing director 2. Natural gas is sent to the primary reformer for steam. Review on dry reforming of methane, a potentially more.
Simulation of methane slippage in steam methane reforming mohd. With the reaction kinetics for msr reported by xu and. The pengrobinson fluid package was chosen for use in the hysys simulation because it is ideal for describing hydrocarbon systems such as the steam methane reforming plant, where most components are gases or are nonpolar. Manual for information concerning reaction types and the addition of reactions. Reforming, catalytic cracking, hydrocracking hydrocracking severe form of hydroprocessing break carbon. Technoeconomic analysis tea for co 2 reforming of methane in a membrane reactor mr was conducted by using process simulation and economic analysis. Methane steam reforming reaction behaviour in a packed bed. The methanol synthesis part which is of importance. The models included all the feed pretreatment steps along with the reforming reactors and effluent treatment. The 16 study series an unprecedented look at methane from the natural gas system methane ch4 is a growing environmental concern. Conventional steam reforming with co capture has been used as a base case for. The autothermal reforming of methane developed using hysys 2006.
Kinetic based simulation of methane steam reforming and water. Optimization of a methane autothermal reformingbased. Hydrogen is predominantly generated from the reaction amongst methane and steam. Kinetics, catalysis and mechanism of methane steam reforming. This chapter describes the process and steadystate simulation of the methane. Within such a context, this work evaluates the technical performance of a novel cmr, which utilizes two catalysts in series, rather than one. Simulation of hydrogen production for mobile fuel cell applications. Post jobs, find pros, and collaborate commissionfree in our professional marketplace. Methane steam reforming reaction behaviour in a packed bed membrane reactor lemnouer chibane and brahim djellouli international journal of chemical engineering and applications, vol. Figure 2 fuel processor plant developed using aspen hysys 2004. This manual is intended as a guide to using aspentechs software.
It represents the eiga contribution to the refineries bref1 being organized by the european ippc2 bureau. Introduction to dynamic process simulation using aspen hysys v10 with a worked example duration. None of the commercial process simulators aspen plus, proii, hysys, etc. Steam methane reforming hydrogen production hysys tutorial. Onsite hydrogen generation by steam methane reforming what its like to be a. Pdf kinetic based simulation of methane steam reforming. May 19, 2011 introduction to dynamic process simulation using aspen hysys v10 with a worked example duration. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high temperature, high steam to methane ratio, and low pressure to achieve maximum conversion. Stabilize steam methane reformer combustion, reduce variability, and gain control of energy costs with emersons steam methane reformer solution, which will enable your operators to respond to changing conditions, keep your equipment from degrading and failing, and help stabilize your reformers performance. Design and evaluation of a heatintegrated hydrogen. Kinetic based simulation of methane steam reforming and water gas shift for hydrogen production using aspen plus article pdf available in chemical engineering transactions 56. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful. The design of the steam reforming process is in part dictated by these constraints. The main reactions associated with the steam methane reforming process.
This paper presents the kineticbased simulation of methane steam reforming msr from natural gas and water gas shift wgs reaction for hydrogen production. The waste heat recovery technique is applied to build a standalone ideal heatintegrated system. Steam methane reforming posted in chemical process simulation. Methane steam reforming reaction behaviour in a packed. May 14, 2010 steammethane reforming is a process in which high temperature steam 700c c is reacted with a methane source usually natural gas at a high pressure of 325 bar with a catylist. Reducing emissions of both methane and carbon dioxide is. This documentation contains aspentech proprietary and. Pdf kinetic based simulation of methane steam reforming and. If anyone is working with modelling of steam methane reforming with. Steam methane reforming chemical process simulation. Simulation, sensitivity analysis and optimization of.
On the stoichiometry tab add all of the components to the. Comparison of exergy losses for reformers involved in hydrogen. The formulaes developed to calculate the methane number are based on the assumption that the methane number curves in figure 2. Aspen hysys 2006 provides tool to design a steady and dynamics state. On the stoichiometry tab select the first row of the component column in stoichiometry info matrix. Methane is almost completely consumed at inlet conditions of the catalyst bed due to the high temperature of gases coming from the combustion zone. Select ethylbenzene from the drop down list in the edit bar. Recovery of co 2 from units of steam methane reforming at. Algorithm for methane number determination for natural gasses.
Author links open overlay panel wei wu a yanchi liou b hsiaotung yang a. Chemical process simulation and the aspen hysys v8. Open a new case by clicking on the blank white page or use the commands file new. The simulation results show that the dualbed autothermal. Reformer modelbased inferential properties embedded in apc page 4 rigorous model the aspen hysys reformer model is based on fundamental kinetics and its integrated with hysys fractionationheat exchange models providing this way a full flowsheet model which is represented in the figure below. Smr based plants are most commonly used to produce a hydrogen product or a combination of a hydrogen stream and. Hysys conversion coefficient for multiple reactions. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states.
Design and evaluation of a heatintegrated hydrogen production system by reforming methane and carbon dioxide. This paper presents the kineticbased simulation of methane steam reforming msr from natural gas and water gas shift wgs reaction for hydrogen. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Carbon dioxide reforming of methane to produce synthesis gas over metalsupported catalysts. Simulation, sensitivity analysis and optimization of hydrogen production by. This site is like a library, use search box in the widget to get ebook that you want. Methane steam reforming, methanation and watergas shift. Please check your email for instructions on resetting your password. Hysys conversion coefficient for multiple reactions posted in chemical process simulation. Monitor the effect of molar flow of steam multiplier of 1. Pdf simulation of hydrogen production for mobile fuel. Aug 28, 2014 the much lower cost of natural gas and the desire to reduce carbon dioxide emissions have stimulated interest in the dry methane reforming process in which these two gases react to produce synthesis gas. Reformer modelbased inferential properties embedded in apc. Most of the methane conversion had been achieved in the half of the catalyst bed.
Modeling and simulation of an industrial secondary. Steam reforming of natural gas wikid energy funhouse. Hydrogen production by steam reforming chemical engineering. Methane is a potent greenhouse gas that is contributing to climate change. H298k 75 kjmol ch4 several parameters have been defined, including dimensions and information on the porous medium. Experiential learning and working with students in the labs 6. The purpose of hses assessment of a safety report against the criteria in the sram, is to come to a conclusion on whether the requirements and demonstrations in schedule 4 part 1 have been met. Science confirms methane is a problem that requires urgent attention. Modeling and simulation of an industrial secondary reformer. Water enters the furnace, producing steam at a very high temperature. Steam reforming of light hydrocarbons, such as natural gas, is the dominant technology for the production of syngas, and thus, of hydrogen.
Dear claud, im intersted in steam reforming as well. A large number of detailed reaction mechanisms were considered. Design and control of the dry methane reforming process. Reforming unit the main reaction occurring in the reformer is the conversion of methane to a mixture of co, co2 and h2. Normally, natural gasses contain methane, ethane, propane, butane, pentane. Learn aspen plus in 24 hours integrating aspen plus into the chemical engineering classroom. Simulation of hydrogen production for mobile fuel cell applications via autothermal reforming of methane. Steam methane reforming is the most widely used process for the generation of hydrogen. Uops polybed psa system produces the highpurity hydrogen needed for the optimum performance of catalytic processes. For the baseline hfa, we compared the costs and efficiencies of two hydrogengeneration technologies steam methane reforming and autothermal reforming and two hydrogen purification. Then select the conversion reaction refer to section 4.
Intrinsic kinetics intrinsic rate equations were derived for the steam reforming of methane, accompanied by watergas shift on a ni mga1204 catalyst. Additional information on hysys thermodynamics packages can be found in the simulation basis manual appendix a. Zn is used in many industries such as the pharmaceutical and food industries. The first section of ptal2o3 catalyst is designed for oxidation reaction, whereas the second one based on nimgal2o4 catalyst involves steam reforming reaction. Jul 28, 20 steam reforming the basics of reforming 1. Sep 19, 2016 palladiumbased catalytic membrane reactors cmrs effectively remove h 2 to induce higher conversions in methane steam reforming msr and watergasshift reactions wgs. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. The scale of the modeling within section 2 is based on a steam methane reforming smr process that produces 719 tonsday of hydrogen. The various hydrogen production schemes were investigated for three different fuels.
The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. The aspen hysys software used for the simulation conducted here does not. Optimization of a methane autothermal reforming bas ed hydrogen production system with low co 2 emissions wei wu,a and chutima tungpanututh b adepartment of chemical engineering, national cheng kung university, tainan 70101, taiwan, r. Results showed that carbon dioxide reforming of methane to synga. Methane steam reforming pdf document methane steam reforming. This reforming process operates at very high severity where the reaction temperatures are in the range of 850950 deg c. Combined steam reforming and partial oxidation of methane to. Kinetic based simulation of methane steam reforming and. The autothermal reforming of methane developed using hysys 2004. Hydrogen from natural gas via steam methane reforming smr. Steam methane reforming is the most common and economical way to make hydrogen. Steam methane reforming of natural gas or naphtha is the most widely used process for commercial production of hydrogen.
Integration of methane steam reforming and water gas shift. Journal of the taiwan institute of chemical engineers. This paper presents a performance analysis of a dualbed autothermal reformer for hydrogen production from methane using a nonisothermal, one dimensional reactor model. Nov 11, 2014 dry reforming of methane in a dielectric barrier discharge reactor with nial 2 o 3 catalyst. Cost and performance comparison of stationary hydrogen. Please guide me with the techniques used and references available. The steam methane reforming process can be broken down into five distinct steps. The hfa is composed of a reforming system including the reformer, gas cleanup system, and peripheral components, a hydrogen compressor, storage tanks, and dispenser. Pdf optimization of a methane autothermal reforming. Jul 19, 2012 methane is almost completely consumed at inlet conditions of the catalyst bed due to the high temperature of gases coming from the combustion zone. Click download or read online button to get aspen hysys book now.
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